Oxometalate-glass composites and thin films

New glass-composites with ion exchange properties have been developed. Ammonium 12-molybdophosphate (AMP) (ΝΗ4)3ΡΜοΐ2θ4ο, and ammonium 12-tungstophosphate (AWP) (Nh4)3PW12O40, known for their ion exchange capabilities, are included either in preformed aerogels with defined pore size, or are added to sol-gel mixtures during the process of gel formation. Characterization is carried out by FTIR, Raman and EXAFS spectroscopy. Ion exchange capacities for the oxometalate precursors are determined for silver and rubidium and are compared to those of the glass composites. Glass composites show high ion exchange capacity, but some portion of the metalate complexes leaches from the glass during the procedure. This is in contrast to thin composite films, which have almost no porosity and do not show loss of metalate. EXAFS spectroscopy demostrates that the oxometalate microstructure is maintained in glass composites and that rubidium ions after ion exchange in glasses occupy similar cation positions as in the precursor compounds

Stabilization of metal ensembles at room temperature. Palladium clusters in zeolites

Palladium clusters of low nuclearity have been prepared in the cavities of X zeolites via ion exchange with Pd(NH,),Cl,, oxidative dehydration, and subsequent reduction of the dry Pd(I1) zeolites with hydrogen at 295 and 425 K. Detailed EXAFS analysis of Pd K-edge data shows that the average first-shell Pd-Pd coordination number of the reduced system is only about N = 1.5 at a distance of 2.78 A. A long, relatively disordered coordination of the reduced Pd to framework oxygen and silicon indicates the stabilizing, templating function of the zeolite matrix. Geometric models based upon the EXAFS results show that intrazeolite Pdz, Pd,, and Pd4 clusters are formed by partial occupation of SI and SII positions of the sodalite subunits of the zeolite. This study presents evidence for the formation of molecular metal ensembles stabilized in an open-framework matrix to at least 425 K

Detection of nanoparticles by means of reflection electron energy loss spectroscopy depth profiling

The various studies of nanoparticles are of great importance because of the wide application of nanotechnology. The shape and structure of the nanoparticles can be determined by transmission electron microscopy (TEM) and their chemistry by electron energy loss spectroscopy. TEM sample preparation is an expensive and difficult procedure, however. Surface sensitive, analytical techniques, such as Auger electron spectroscopy (AES) and x-ray photoelectron spectroscopy (XPS) are well applicable to detect the atoms that make up the nanoparticles, but cannot determine whether particle formation occurred. On the other hand, reflection electron energy loss spectroscopy (REELS) probes the electronic structures of atoms, which are strongly different for the atoms being in solution or in precipitated form. If the particle size is in the nm range, plasmon resonance can be excited in it, which appears as a loss feature in REELS spectrum. Thus, by measuring AES (XPS) spectra parallel with those of REELS, besides the atomic concentrations the presence of the nanoparticles can also be identified. As an example, the appearance of nanoparticles during ion beam induced mixing of C/Si layer will be shown

A p-multigrid method enhanced with an ILUT smoother and its comparison to h-multigrid methods within Isogeometric Analysis

Over the years, Isogeometric Analysis has shown to be a successful alternative to the Finite Element Method (FEM). However, solving the resulting linear systems of equations efficiently remains a challenging task. In this paper, we consider a p-multigrid method, in which coarsening is applied in the approximation order p instead of the mesh width h. Since the use of classical smoothers (e.g. Gauss-Seidel) results in a p-multigrid method with deteriorating performance for higher values of p, the use of an ILUT smoother is investigated. Numerical results and a spectral analysis indicate that the resulting p-multigrid method exhibits convergence rates independent of h and p. In particular, we compare both coarsening strategies (e.g. coarsening in h or p) adopting both smoothers for a variety of two and threedimensional benchmarks

Effects of haloperidol and atypical neuroleptics on psychomotor performance and driving ability in schizophrenic patients - Results from an experimental study

The influence of antipsychotic treatment on the neuropsychological and psychomotor performance of schizophrenic patients is still a subject of investigation. The present study was designed to evaluate the effects of atypical neuroleptics in comparison with a conventional dopamine antagonist neuroleptic (haloperidol) on several dimensions of psychomotor performance (visual perception, attention, reaction time, and sensorimotor performance) considered to be of relevance in evaluating driving fitness. Psychomotor performance was assessed by means of the ART 90, a computerized Act and React Test which is generally used in diagnosis of psychomotor performance. The 49 participating patients were examined at discharge following psychopathological stabilisation; 20 received haloperidol, 29 received an atypical neuroleptic. Our findings demonstrate a remarkably reduced psychomotor performance in the haloperidol-treated group of schizophrenic patients compared with patients treated with atypical neuroleptics. Only 1 (5%) subject passed all subtests without major failures and could be regarded as competent to drive. Among patients with atypical neuroleptics, 7 patients (24%) passed all test parameters without major failures. Copyright (C) 2003 S. Karger AG, Basel

Electromagnetic and transient shielding effectiveness for near-field sources

The contribution deals with an investigation of the recently proposed definitions for the electromagnetic and transient shielding effectiveness (SE) in the case of an electric-dipole near-field source. To this end, new factors are introduced which depend on the distance between the dipole source and the measurement point inside the shield and which are valid for perpendicularly (with respect to the distance vector) polarized dipoles. Numerical results support and confirm the theoretical derivations